Product ID:6932, 6940. 6950, BLEND
MSDS Date:04/04/1986
FSC:6850
NIIN:00D020285
MSDS Number: CCLMG

VALVOLINE OIL CO SUBSIDIARY OF ASHLAND OIL INC.

200 E MAIN ST
LEXINGTON, KY 40512
US

Emergency Phone: 800-ASHLAND/800-274-5263

Info Phone: 606-264-7000/7616;FAX 601-429-0537

Cage: 72527

VALVOLINE OIL CO

14000 LEXINGTON, KY 40512 US

Telephone: 606-357-7206 / 800-274-5263

Cage: 72527

METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA 313)

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 70-85%

OSHA PEL 350 PPM

ACGIH TLV: 350 PPM/450STEL;9495

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

HEAVY NAPHTHA SOLVENT EXTRACT

CAS: 64741-98-6

Fraction By Weight: 10-15%

ALIPHATIC PETROLEUM SOLVENT

CAS: 8008-20-6

RTECS: OA5500000

Fraction By Weight: 1-5%

2-BUTOXYETHANOL

CAS: 111-76-2

RTECS: KJ8575000

Fraction By Weight: 1-5%

OSHA PEL S, 50 PPM

ACGIH TLV: S, 25 PPM; 9495

LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES:CAN CAUSE SEVERE IRRITATION,
REDNESS, TEARING, BLURRED VISION. SKIN:PROLONGED &/OR REPEATED
CONTACT IRRITATION. BREATHING:CAN CAUSE NASAL & RESPIRATORY
IRRITATION, CNS EFFECTS. SWALLOWING:CAN CAU SE G/I IRRITATION,
NAUSEA, VOMITING, DIARRHEA. ASPIRATION INTO LUNGS CAN CAUSE
CHEMICAL PNEUMONITIS WHICH MAY BE FATAL.
Explanation of Carcinogenicity:MANUFACTURER GAVE NO INFORMATION ABOUT
CARCINOGENICITY. HMIS FOUND NO LISTING & DOES NOT EXPECT IT TO BE
CARCINOGENIC.
Effects of Overexposure:MFR GAVE NO INFORMATION OF MSDS.
Medical Cond Aggravated by Exposure:MFR GAVE NO INFORMATION OF MSDS.

First Aid:IF ANY IRRITATION PERSISTS OR SEVERE, GET MEDICAL ATTENTION.
EYE:FLUSH W/WATER FOR 15 MIN, LIFITING LIDS OCCASIONALLY. SKIN:WASH
THOROUGHLY W/SOAP & WATER. INHALED:NOT APPLICABLE. INGESTED:DO NOT
INDU CE VOMITING. KEEP VICTIM QUIET & GET IMMEDIATE MEDICAL
ATTENTION. ASPIRATION OF MATERIAL INTO LUNGS DUE TO VOMITING CAN
CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. DO NOT GIVE
STIMULANTS.

Flash Point Method:TCC
Flash Point:145F,63C
Autoignition Temp:Autoignition Temp Text:N/A.
Lower Limits:1.0
Upper Limits:UNAVAILABLE
Extinguishing Media:REGULAR FOAM, CARBON DIOXIDE, DRY CHEMICAL
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS W/FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE DEMAND MODE WHEN FIGHTING
FIRES. WATER/FOAM MAY CAUSE FROTHING.
Unusual Fire/Explosion Hazard:NEVER USE TORCH ON DURM (EVEN EMPTY).
PRODUCT MAY IGNITE EXPLOSIVELY. MAY FORM TOXIC MATERIALS:CARBON
MONOXIDE, CARBON DIOXIDE, VARRIOUS HYDROCARBONS.

Spill Release Procedures:SMALL SPILL:SWEEP MATERIAL ONTO PAPER, ETC &
TRANSFER TO HOOD. LARGE SPILL:ELIMINATE IGNITION SOURCES. EVACUATE
AREA. STOP SPILL & DIKE. RECOVER LIQUID. ABSORB REMAINDER W/INERT
MATERIAL & SHOVEL INTO CONTAINERS. PREVENT RUN OFF TO SEWERS &
WATER.
Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS.

Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT
RESIDUES, FOLLOW ALL PRECAUTIONS IN THIS DATASHEET.
Other Precautions:NONE

Respiratory Protection:IF EXPOSURE LIMIT OF PRODUCT OR ANY COMPONENT IS
EXCEEDED, USE A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IN THE
ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA REGULATIONS PERMIT
OTHER RESPIRATORS U NDER SPECIFIED CONDITIONS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL) VENTILATION TO KEEP
EXPOSURE Protective Gloves:WEAR RESISTANT GLOVES, NITRILE, RUBBER
Eye Protection:CHEMICAL SPLASH GOGGLES (OSHA PERMITTED)
Other Protective Equipment:TO PREVENT PROLONGED &/OR REPEATED SKIN
CONTACT, WEAR IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:MFR GAVE NO INFORMATION OF MSDS.
Supplemental Safety and Health
CHRONIC HEALTH EFFECTS-CONTAINS KEROSENE. SIMILAR MATERIALS HAVE CAUSED
SKIN CANCER IN LAB ANIMALS. SEE INDIVIDUAL REPORTS. ** HAS CAUSED
LIVER ABNORMALITIES, KIDNEY DAMAGE, LUNG DAMAGE, ANEMIA, BLOOD
ABNORMALITIES IN LAB ANIMALS ** SUGGESTED TO HAVE CAUSED LIVER &
HEART ABFNORMALITIES, KIDNEY & LUNG DAMAGE IN HUMANS.

HCC:V4
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:161F,72C
Vapor Pres:100 MM
Vapor Density:>1
Spec Gravity:1.155
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:CLEAR, LIGHT BLUE LIQUID, HOMOG SOLN
Percent Volatiles by Volume:>95

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/STRONG OXIDIZING AGENTS
Stability Condition to Avoid:MFR GAVE NO INFORMATION OF MSDS.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE
Conditions to Avoid Polymerization:CANNOT OCCUR

Waste Disposal Methods:SMALL SPILL:ALLOW TO EVAPORATE IN HOOD. DISPOSE
OF REMAINDER I/A/W APPLICABLE REGULATIONS. LARGE SPILL:DESTROY BY
LIQUID INCINERATION. CONTAMINATED ABSORBENT MAY BE DEPOSITED IN
LANDFILL I/A/W FEDERAL , STATE & LOCAL REGULATIONS.

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